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ICQ's features could fill a book and include "awareness" (the ability to determine whether other people are online at a given moment).
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To help you stay safe, chats are anonymous unless you tell someone who you are (not suggested! Predators have been known to use Omegle, so please be careful.
If you prefer, you can add your interests, and Omegle will look for someone who's into some of the same things as you instead of someone completely random.
Then check out this site, which offers loads of free goodies to help you make the most of Messenger, including thousands of emoticons and avatars.